Issue 13, 2013
From the journal:

Physical Chemistry Chemical Physics

Conformal growth of nanocrystalline CdX (X = S, Se) on mesoscopic NiO and their photoelectrochemical properties†

Fatemeh Safari-Alamuti,ab   James R. Jennings,a   Md. Anower Hossain,a   Lin Yue Lanry Yungb  and  Qing Wang*a  

* Corresponding authors

a Department of Materials Science and Engineering, Faculty of Engineering, NUSNNI-NanoCore, National University of Singapore, Singapore
E-mail: qing.wang@nus.edu.sg

b Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore, Singapore

Abstract

Semiconductor-sensitized NiO photocathodes have been fabricated by successive ionic-layer adsorption and reaction (SILAR) deposition of CdS, CdSe and cascaded CdS/CdSe onto mesoscopic NiO films. Detailed morphological and structural characterization reveals that the growth of CdS and CdSe on mesoscopic NiO electrodes results in the formation of crystalline and conformal layers under ambient conditions. With a polysulfide redox electrolyte and a Pt counter electrode, CdX (X = S and Se)-sensitized p-NiO solar cells operating in a photocathodic mode are unambiguously demonstrated when NiO blocking layers are used, which are critical to prevent anodic photocurrent due to electron injection from CdX into the SnO2:F substrate. To decrease the recombination rate, a CdS barrier layer was deposited between NiO and a CdSe sensitizer which results in much enhanced cell performance. Front and rear spectral incident photon-to-current efficiency (IPCE) measurements were used to investigate charge collection and separation in the cells. The measurements indicate that charge collection in this system is limited by a short hole diffusion length.

Graphical abstract: Conformal growth of nanocrystalline CdX (X = S, Se) on mesoscopic NiO and their photoelectrochemical properties

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Article information

DOI
https://doi.org/10.1039/C3CP43613F
Article type
Paper
Submitted
12 Oct 2012
Accepted
05 Feb 2013
First published
05 Feb 2013

Phys. Chem. Chem. Phys., 2013,15, 4767-4774

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Conformal growth of nanocrystalline CdX (X = S, Se) on mesoscopic NiO and their photoelectrochemical properties

F. Safari-Alamuti, J. R. Jennings, Md. A. Hossain, L. Y. L. Yung and Q. Wang, Phys. Chem. Chem. Phys., 2013, 15, 4767 DOI: 10.1039/C3CP43613F

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