Issue 17, 2014

Size- effect induced high thermoelectric figure of merit in PbSe and PbTe nanowires

Abstract

The fundamental properties that compose the thermoelectric figure of merit are investigated in the confined systems of PbSe and PbTe nanowires, with the goal to improve the thermoelectric efficiency. Using the Landauer electronic transport theory, we verify that the figure of merit can be several times larger than the bulk value for nanowires with diameters down to the one nanometer scale. This enhancement in the thermoelectric efficiency is primarily due to the reduction of the thermal conductivity and an increase in the power factor. The origin of these desireable properties, that enable the transformation of heat into electricity, comes from the confinement effect which increases the density of states around the Fermi level, either for an n- or p-type system.

Graphical abstract: Size- effect induced high thermoelectric figure of merit in PbSe and PbTe nanowires

Article information

Article type
Paper
Submitted
11 Dec 2013
Accepted
10 Feb 2014
First published
10 Feb 2014

Phys. Chem. Chem. Phys., 2014,16, 8114-8118

Author version available

Size- effect induced high thermoelectric figure of merit in PbSe and PbTe nanowires

E. O. Wrasse, A. Torres, R. J. Baierle, A. Fazzio‡ and T. M. Schmidt, Phys. Chem. Chem. Phys., 2014, 16, 8114 DOI: 10.1039/C3CP55233K

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