Issue 3, 2014

Enhanced photocatalytic activity over the Ag2O–g-C3N4 composite under visible light

Abstract

The Ag2O–g-C3N4 composite was prepared by the coprecipitation method and was well characterized by X-ray diffraction, transmission electron microscopy with energy dispersion X-ray spectroscopy, UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, photoluminescence spectroscopy and surface photovoltage spectroscopy. The photocatalytic activities were evaluated in the degradation of Rhodamine B aqueous solution. The results showed that Ag2O sized 5–10 nm was highly anchored on the surface of the pure g-C3N4 support, causing the Ag2O–g-C3N4 composite to show stronger absorption in the visible light region and higher photocatalytic activities than pure g-C3N4 and Ag2O. The enhanced photocatalytic activities were attributed to combined effects, including highly dispersed smaller Ag2O particles, stronger visible absorption and higher charge separation efficiency. The possible mechanism for the photocatalytic activity of Ag2O–g-C3N4 was tentatively proposed.

Graphical abstract: Enhanced photocatalytic activity over the Ag2O–g-C3N4 composite under visible light

Article information

Article type
Paper
Submitted
01 Nov 2013
Accepted
04 Dec 2013
First published
05 Dec 2013

Catal. Sci. Technol., 2014,4, 758-765

Enhanced photocatalytic activity over the Ag2O–g-C3N4 composite under visible light

L. Shi, L. Liang, J. Ma, F. Wang and J. Sun, Catal. Sci. Technol., 2014, 4, 758 DOI: 10.1039/C3CY00871A

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