Issue 48, 2013
From the journal:

Dalton Transactions

The “Fenton like” reaction of MoO43− involves two H2O2 molecules

Inna Popivker,ab   Israel Zilbermann,ab   Eric Maimon,ab   Haim Cohenc  and  Dan Meyerstein*ac  

* Corresponding authors

a Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel
E-mail: danmeyer@bgu.ac.il
Fax: +972 8 6472943
Tel: +972 8 6472737

b Chemistry Department, Nuclear Research Centre Negev, Beer-Sheva, Israel

c Biological Chemistry Department, Ariel University, Ariel, Israel

Abstract

Surprisingly the oxidation of MoO43− by H2O2 involves two H2O2 molecules. It is proposed that generally when the reaction of a reducing agent with H2O2, to form a single electron oxidized product and a hydroxyl radical, is endothermic the reaction involves more than one H2O2 molecule.

Graphical abstract: The “Fenton like” reaction of MoO43− involves two H2O2 molecules

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Article information

DOI
https://doi.org/10.1039/C3DT52333K
Article type
Communication
Submitted
26 Aug 2013
Accepted
17 Sep 2013
First published
18 Sep 2013

Dalton Trans., 2013,42, 16666-16668

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The “Fenton like” reaction of MoO43− involves two H2O2 molecules

I. Popivker, I. Zilbermann, E. Maimon, H. Cohen and D. Meyerstein, Dalton Trans., 2013, 42, 16666 DOI: 10.1039/C3DT52333K

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