Issue 25, 2014

Elimination of ibuprofen and its relative photo-induced toxicity by mesoporous BiOBr under simulated solar light irradiation

Abstract

3D mesoporous BiOBr microspheres via a one-step solvothermal process without templates were synthesized. The as-synthesized material was characterized by XRD, XPS, FESEM, TEM, UV-Vis and nitrogen adsorption techniques. The photodegradation behavior of the non-steroid anti-inflammatory drug (NSAID) ibuprofen (IBP) in aqueous BiOBr suspension was investigated under simulated solar light irradiation. The photocatalytic activity of the as-prepared 3D mesoporous BiOBr microspheres was excellent. IBP photodegradation intermediates were detected by GC/MS analyses, and a detailed reaction pathway was proposed. Luminous bacteria (Vibrio qinghaiensis) toxicity evaluation showed the decrease of the toxicity of the photodegradation intermediates. Based on the results, 3D BiOBr could be a promising catalyst on irradiation by visible light, and even under sunlight.

Graphical abstract: Elimination of ibuprofen and its relative photo-induced toxicity by mesoporous BiOBr under simulated solar light irradiation

Article information

Article type
Paper
Submitted
04 Dec 2013
Accepted
24 Jan 2014
First published
06 Mar 2014

RSC Adv., 2014,4, 13061-13070

Elimination of ibuprofen and its relative photo-induced toxicity by mesoporous BiOBr under simulated solar light irradiation

H. Tian, Y. Fan, Y. Zhao and L. Liu, RSC Adv., 2014, 4, 13061 DOI: 10.1039/C3RA47304J

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