Issue 18, 2014
From the journal:

RSC Advances

N-Allylation of amines with allyl acetates using chitosan-immobilized palladium†

R. B. Nasir Baig,a   Buchi R. Vaddula,a   Michael A. Gonzaleza  and  Rajender S. Varma*a  

* Corresponding authors

a Sustainable Technology Division, National Risk Management Research Laboratory, U. S. Environmental Protection Agency, 26 West Martin Luther King Drive, MS 443, Cincinnati, Ohio 45268, USA
E-mail: Varma.Rajender@epa.gov
Fax: +1 513-569-7677
Tel: +1 513-487-2701

Abstract

A simple procedure for N-allylation of amines with allyl acetates has been developed using a biodegradable and easily recyclable heterogeneous chitosan-supported palladium catalyst. The general methodology, applicable to a wide range of substrates, has sustainable features that include a ligand-free reaction with simple workup, recycling and reusability of the catalyst.

Graphical abstract: N-Allylation of amines with allyl acetates using chitosan-immobilized palladium

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Article information

DOI
https://doi.org/10.1039/C3RA47899H
Article type
Communication
Submitted
23 Dec 2013
Accepted
15 Jan 2014
First published
20 Jan 2014

RSC Adv., 2014,4, 9103-9106

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N-Allylation of amines with allyl acetates using chitosan-immobilized palladium

R. B. Nasir Baig, B. R. Vaddula, M. A. Gonzalez and R. S. Varma, RSC Adv., 2014, 4, 9103 DOI: 10.1039/C3RA47899H

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