Issue 62, 2014
From the journal:

Chemical Communications

Direct evidence by in situ IR CO monitoring of the formation and the surface segregation of a Pt–Sn alloy†

Alina Moscu,a   Yves Schuurman,a   Laurent Veyre,b   Chloé Thieuleuxb  and  Frederic Meunier*a  

* Corresponding authors

a Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON), Université Lyon 1, CNRS, 2, Av. Albert Einstein, F-69626 Villeurbanne, France
E-mail: frederic.meunier@ircelyon.univ-lyon1.fr
Fax: +33 4 72 44 53 65

b Université de Lyon, Institut de Chimie de Lyon, LC2P2, UMR 5265 CNRS-CPE Lyon-UCBL, CPE Lyon, 43 Bvd du 11 Novembre 1918, 69100 Villeurbanne, France

Abstract

The heat of CO adsorption on the Pt atoms of a Pt–Sn alloy phase could be specifically determined from in situ DRIFTS data and was found to be about half that measured on a plain Pt reference. Surprisingly, a reversible surface segregation of the Pt–Sn alloy was observed at temperatures below 175 °C.

Graphical abstract: Direct evidence by in situ IR CO monitoring of the formation and the surface segregation of a Pt–Sn alloy

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC03208J
Article type
Communication
Submitted
29 Apr 2014
Accepted
11 Jun 2014
First published
11 Jun 2014

Chem. Commun., 2014,50, 8590-8592

Permissions

Request permissions

Direct evidence by in situ IR CO monitoring of the formation and the surface segregation of a Pt–Sn alloy

A. Moscu, Y. Schuurman, L. Veyre, C. Thieuleux and F. Meunier, Chem. Commun., 2014, 50, 8590 DOI: 10.1039/C4CC03208J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements