Issue 29, 2014
From the journal:

Journal of Materials Chemistry A

AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid†

Hongmei Dai,a   Nan Cao,a   Lan Yang,a   Jun Su,c   Wei Luo*ab  and  Gongzhen Chenga  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, P. R. China
E-mail: wluo@whu.edu.cn
Tel: +86 2768752366

b Suzhou Institute of Wuhan University, Suzhou, Jiangsu, P. R. China

c Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan, Hubei, P. R. China

Abstract

Bimetallic AgPd nanoparticles were successfully immobilized into the metal–organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid. These catalysts were composition dependent for the catalytic activity. Among all the AgPd@MIL-101 catalysts tested, the Ag20Pd80@MIL-101 catalyst exhibits the highest catalytic activity for the conversion of formic acid to high-quality hydrogen at 80 °C with a TOF value of 848 h−1, which is among the highest values reported at 80 °C.

Graphical abstract: AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid

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Article information

DOI
https://doi.org/10.1039/C4TA02066A
Article type
Communication
Submitted
25 Apr 2014
Accepted
16 May 2014
First published
21 May 2014

J. Mater. Chem. A, 2014,2, 11060-11064

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AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid

H. Dai, N. Cao, L. Yang, J. Su, W. Luo and G. Cheng, J. Mater. Chem. A, 2014, 2, 11060 DOI: 10.1039/C4TA02066A

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