In this study, the characterization and photocatalytic activity of Bi₂WO₆/Bi₂O₃ loaded reduced graphene oxide under visible-light irradiation was investigated in detail. The results suggested that the Bi₂WO₆/Bi₂O₃ loaded reduced graphene oxide can be synthesized by a facile one-step solvothermal process. Through the characterization of the composite photocatalyst by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared, UV-vis diffuse reflectance spectra and photoluminescence spectra, it was found that Bi₂WO₆/Bi₂O₃@RGO composite was formed, meanwhile GO was completely reduced to graphene and bonded with Bi₂WO₆/Bi₂O₃ with by C–O to form composite. The as-prepared composite owned enhanced absorption in the UV to visible-light region and exhibited decreased radiative recombination of photogenerated charge carriers. Moreover, it was expected that the as-prepared composites exhibited enhanced photocatalytic activity for the degradation of Rhodamine B under visible-light irradiation. Among them, BWO@R3 (GO% = 5%) owned the best photocatalytic activity, which can photodegrade RhB (10⁻² g L⁻¹) reaching 99.6% in 20 min and high concentration RhB (30⁻² g L⁻¹) reaching 99.2% in 180 min. It can be ascribed to their improved light absorption property and the reduced recombination of the photogenerated electron–holes during the photocatalytic reaction.