Issue 3, 1974

Crystal and molecular structure of cadmium(II) cyanoacetate

Abstract

Crystals of the title compound are monoclinic, a= 4·465(1), b= 10·262(2), c= 17·567(5)Å, β= 95·44(2)°, Z= 4, space group P21/n. The structure was determined from X-ray diffractometer data by Patterson and Fourier syntheses, and refined by full-matrix least-squares calculations to R 0·046 for 1656 observed reflections. The cadmium is co-ordinated to one nitrogen and five oxygen atoms in distorted octahedral geometry. Each of the two independent cyanoacetate ligands co-ordinates to three symmetry-related cadmium atoms to give a three-dimensional polymeric lattice. One ligand co-ordinates through two oxygen atoms, one of which is also bridging, while the other co-ordinates through two oxygen atoms and the nitrogen atom. In common with many other acetates, the metal atom is not chelated, the ligands acting as bridging molecules.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 285-288

Crystal and molecular structure of cadmium(II) cyanoacetate

M. L. Post and J. Trotter, J. Chem. Soc., Dalton Trans., 1974, 285 DOI: 10.1039/DT9740000285

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