Issue 4, 1988
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Time-resolved analysis of a ‘crystal-like’ structure-forming process of a monodisperse polystyrene sphere as studied by rapid-scanning spectrophotometry

Tsuneo Okubo  

Abstract

Time-resolved transmitted-light spectra are obtained during the reappearance of the ‘crystal-like’ structure of a deionized polystyrene sphere after the rapid flow through a thin optical cell is stopped. Fast formation of metastable ordered structures finishes within 100 ms. Formation of the stable structure is attained after more than 1 s. Transformation of the lattice structure from face-centred cubic to body-centred cubic lattices is sometimes observed in the course of structure formation. These results support the idea that electrostatic intersphere repulsion in the effective hard-sphere model is essential to explain the ordering.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/F19888401163
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1988,84, 1163-1169

Permissions

Request permissions

Time-resolved analysis of a ‘crystal-like’ structure-forming process of a monodisperse polystyrene sphere as studied by rapid-scanning spectrophotometry

T. Okubo, J. Chem. Soc., Faraday Trans. 1, 1988, 84, 1163 DOI: 10.1039/F19888401163

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements