PES bands due to ionization from n*, n and π orbitals of the NO group in some aliphatic nitroso compounds have been identified. In nitrosobenzene derivatives only the n*(NO) band can be assigned unequivocally. Substituent effects on the ionization energies in aliphatic and aromatic nitroso compounds have been correlated with substituent constants.
R. Egdell, J. C. Green, C. N. R. Rao, B. G. Gowenlock and J. Pfab, J. Chem. Soc., Faraday Trans. 2, 1976, 72, 988 DOI: 10.1039/F29767200988
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