Phase diagrams and crystal chemistry in the Li+ ion conducting perovskites, Li0.5 – 3xRE0.5 +xTiO3 : ReLa, Nd

A. D. Robertson; S. Garcia Martin; A. Coats; A. R. West

doi:10.1039/JM9950501405

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Phase diagrams and crystal chemistry in the Li⁺ ion conducting perovskites, Li_{0.5 – 3x}RE_{0.5 +x}TiO₃ : ReLa, Nd

A. D. Robertson, S. Garcia Martin, A. Coats and A. R. West

Abstract

The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li_{0.5 – 3x}RE_{0.5 +x}TiO₃: RE [triple bond, length half m-dash] La, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in the Nd system) are presented, together with data on the composition and thermal history dependence of the lattice parameters. The phase composition and microstructure of selected ceramic samples were analysed by electron microprobe techniques.

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DOI: https://doi.org/10.1039/JM9950501405
Article type: Paper

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J. Mater. Chem., 1995,5, 1405-1412

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Phase diagrams and crystal chemistry in the Li⁺ ion conducting perovskites, Li_{0.5 – 3x}RE_{0.5 +x}TiO₃ : ReLa, Nd

A. D. Robertson, S. G. Martin, A. Coats and A. R. West, J. Mater. Chem., 1995, 5, 1405 DOI: 10.1039/JM9950501405

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Journal of Materials Chemistry

Phase diagrams and crystal chemistry in the Li⁺ ion conducting perovskites, Li_{0.5 – 3x}RE_{0.5 +x}TiO₃ : ReLa, Nd

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Phase diagrams and crystal chemistry in the Li⁺ ion conducting perovskites, Li_{0.5 – 3x}RE_{0.5 +x}TiO₃ : ReLa, Nd

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