Issue 10, 1996
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Solute–solvent and solvent–solvent interactions in binary solvent mixtures. Part 4. Preferential solvation of solvatochromic indicators in mixtures of 2-methylpropan-2-ol with hexane, benzene, propan-2-ol, ethanol and methanol

Elisabeth Bosch,   Fernando Rived  and  Martí Rosés  

Abstract

The Dimroth–Reichardt ET(30) betaine dye, 4-nitroanisole, 4-nitroaniline and N,N-diethyl-4-nitroaniline have been used to study preferential solvation in binary mixtures of 2-methylpropan-2-ol with hexane, benzene, propan-2-ol, ethanol and methanol at 30 °C over the whole range of solvent compositions. A theoretical equation which takes into account the solute–solvent and the solvent–solvent interactions has been successfully employed to correlate the experimental values with solvent composition. The indicators have been used to compute the Dimroth–Reichardt ET(30), and Kamlet–Taft π*, α and β solvatochromic parameters of the mixtures.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P29960002177
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1996, 2177-2184

Permissions

Request permissions

Solute–solvent and solvent–solvent interactions in binary solvent mixtures. Part 4. Preferential solvation of solvatochromic indicators in mixtures of 2-methylpropan-2-ol with hexane, benzene, propan-2-ol, ethanol and methanol

E. Bosch, F. Rived and M. Rosés, J. Chem. Soc., Perkin Trans. 2, 1996, 2177 DOI: 10.1039/P29960002177

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements