Volume 65, 1969

Catalytic oxidation of methane over noble metals

Abstract

The complete oxidation of methane over palladium, platinum, rhodium and iridium has been studied using a microcalorimetric technique. The results indicated that methane may be adsorbed on two types of reaction site, one of which also adsorbs oxygen. The activation energies are proportional to the Pauling bond energies of the oxygen-metal bond in the region where the order in oxygen is low.

Article information

Article type
Paper

Trans. Faraday Soc., 1969,65, 1121-1127

Catalytic oxidation of methane over noble metals

J. G. Firth and H. B. Holland, Trans. Faraday Soc., 1969, 65, 1121 DOI: 10.1039/TF9696501121

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