Abstract
The minimum mass that a virialized gas cloud must have in order to be able to cool in a Hubble time is computed, using a detailed treatment of the chemistry of molecular hydrogen. With a simple model for halo profiles, we reduce the problem to that of numerically integrating a system of chemical equations. The results agree well with numerically expensive three-dimensional simulations, and our approach has the advantage of being able to explore large regions of parameter space rapidly. The minimum baryonic mass Mb is found to be strongly redshift dependent, dropping from 106 M☉ at z ~ 15 to 5 × 103 M☉ at z ~ 100 as molecular cooling becomes effective. For z ≫ 100, Mb rises again, as cosmic microwave background photons inhibit H2 formation through the H- channel. Finally, for z ≫ 200, the H+2 channel for H2 formation becomes effective, driving Mb down toward Mb ~ 103 M☉. With a standard cold dark matter power spectrum with σ8 = 0.7, this implies that a fraction 10-3 of all baryons may have formed luminous objects by z = 30, which could be sufficient to reheat the universe.