Evidence of electron exchange between Fe2+ and Fe3+ ions on tetrahedral and octahedral sites in Fe2MoO4

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Published under licence by IOP Publishing Ltd
, , Citation M P Gupta et al 1979 J. Phys. C: Solid State Phys. 12 2401 DOI 10.1088/0022-3719/12/12/025

0022-3719/12/12/2401

Abstract

Enriched Fe2MoO4 spinel was studied by Mossbauer spectroscopy in the temperature interval of 77-732K. The electrical conductivity measurements were carried out in the temperature range 298-475K. From these studies, it was concluded that fast electron exchange takes place amongst Fe3+ and Fe2+ ions situated at A as well as at B sites in the spinel lattice. The transition temperature TN=350K was determined by the temperature scanning method.

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