The role of 180° domain kinetics on size effects in ferroelectric thin films is studied within a time-dependent Ginzburg-Landau framework. The model incorporates the effect of the depolarization field by considering nonferroelectric-passive layers at the top and bottom surfaces. A critical length scale is predicted below which a depolarization field-induced spontaneous transition from a single domain to a 180° domain pattern causes a time-dependent relaxation of the remnant polarization. This is consistent with the experiments by Kim et al. [Phys. Rev. Lett. 95, 237602 (2005)], where a frequency dependence of the remnant polarization has indeed been observed.

• Received 26 September 2007

DOI:https://doi.org/10.1103/PhysRevB.76.174121