Modes of counterion density fluctuations and counterion-mediated attractions between like-charged fluid membranes

Bae-Yeun Ha
Phys. Rev. E 64, 031507 – Published 30 August 2001
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Abstract

Counterion-mediated attractions between like-charged fluid membranes are long ranged and nonpairwise additive at high temperatures. At low temperatures, however, they are pairwise additive, and decay exponentially with the membrane separation. Using a simple model for the electrostatic attraction between like-charged surfaces, we show that the nature of these attractions is determined by the dominant modes of fluctuations in the density of counterions. While the nonpairwise additive interactions arise from long-wavelength fluctuations and vanish at zero temperature, the short-ranged pairwise additive interactions arise from short-wavelength fluctuations and are stronger at low temperatures.

  • Received 15 September 2000

DOI:https://doi.org/10.1103/PhysRevE.64.031507

©2001 American Physical Society

Authors & Affiliations

Bae-Yeun Ha

  • Department of Physics, Simon Fraser University, Burnaby, British Columbia, Canada V5A 1S6

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Vol. 64, Iss. 3 — September 2001

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