Stress Enhancement in the Delayed Yielding of Colloidal Gels

Joris Sprakel, Stefan B. Lindström, Thomas E. Kodger, and David A. Weitz
Phys. Rev. Lett. 106, 248303 – Published 17 June 2011

Abstract

Networks of aggregated colloidal particles are solidlike and can sustain an applied shear stress while exhibiting little or no creep; however, ultimately they will catastrophically fail. We show that the time delay for this yielding decreases in two distinct exponential regimes with applied stress. This behavior is universal and found for a variety of colloidal gel systems. We present a bond-rupture model that quantitatively describes this behavior and highlights the role of mesoscopic structures. Our result gives new insight into the nature of yielding in these soft solid materials.

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  • Received 3 March 2011

DOI:https://doi.org/10.1103/PhysRevLett.106.248303

© 2011 American Physical Society

Authors & Affiliations

Joris Sprakel*, Stefan B. Lindström, Thomas E. Kodger, and David A. Weitz

  • School of Engineering and Applied Sciences, Harvard University, 9 Oxford Street, Cambridge, 02138 Massachusetts, USA

  • *joris.sprakel@gmail.com

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Vol. 106, Iss. 24 — 17 June 2011

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