Scaling of the Viscoelasticity of Weakly Attractive Particles

V. Trappe and D. A. Weitz
Phys. Rev. Lett. 85, 449 – Published 10 July 2000
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Abstract

The rheological data of weakly attractive colloidal particles are shown to exhibit a surprising scaling behavior as the particle volume fraction, φ, or the strength of the attractive interparticle interaction, U, are varied. There is a critical onset of a solid network as either φ or U increase above critical values. For all solidlike samples, both the frequency-dependent linear viscoelastic moduli, and the strain-rate dependent stress can be scaled onto universal master curves. A model of a solid network interspersed in a background fluid qualitatively accounts for this behavior.

  • Received 14 March 2000

DOI:https://doi.org/10.1103/PhysRevLett.85.449

©2000 American Physical Society

Authors & Affiliations

V. Trappe* and D. A. Weitz

  • Department of Physics and DEAS, Harvard University, Cambridge, Massachusetts 02138

  • *Current address: Department of Physics, University of Fribourg, Fribourg, Switzerland.

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Vol. 85, Iss. 2 — 10 July 2000

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