Abstract
Neutron diffraction and bulk measurements are used to determine the nature of the low-temperature ordered state in , a spin-chain compound with competing interactions. The spin structure is found to be helimagnetic, with a propagation vector , . The nearest-neighbor exchange constant and frustration ratio are estimated to be and , respectively. For idealized quantum spin chains, these parameter values would signify a gapped spin-liquid ground state with commensurate spin correlations. The observed temperature dependence of the magnetic propagation vector in is attributed to a competition between incommensurate helimagnetism in the classical spin model and commensurability in the quantum case. It is also proposed that long-range ordering in is facilitated by intrinsic nonstoichiometry.
- Received 6 October 2003
DOI:https://doi.org/10.1103/PhysRevLett.92.177201
©2004 American Physical Society