Coherently Controlled Asymmetric Synthesis with Achiral Light

Moshe Shapiro, Einat Frishman, and Paul Brumer
Phys. Rev. Lett. 84, 1669 – Published 21 February 2000; Erratum Phys. Rev. Lett. 91, 129902 (2003)
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Abstract

A laser-based method of increasing the enantiomeric excess of a chiral enantiomer in a racemic mixture is described. Neither the initial reagents nor the incident light need be chiral. Both formal and computational results show that enhancement of the enantiomer of choice, controlled by laser parameters, can be extensive.

  • Received 10 June 1999

DOI:https://doi.org/10.1103/PhysRevLett.84.1669

©2000 American Physical Society

Erratum

Erratum: Coherently Controlled Asymmetric Synthesis with Achiral Light [Phys. Rev. Lett. 84, 001669 (2000)]

Moshe Shapiro, Einat Frishman, and Paul Brumer
Phys. Rev. Lett. 91, 129902 (2003)

Authors & Affiliations

Moshe Shapiro and Einat Frishman

  • Chemical Physics Department, The Weizmann Institute of Science, Rehovot, Israel 76100

Paul Brumer

  • Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto, Canada M5S 3H6

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Issue

Vol. 84, Iss. 8 — 21 February 2000

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