Abstract
The paramagnetic resonance spectrum of molybdenum in rutile (Ti) has been studied. The crystal contained 0.05 molar percent molybdenum ions, and the experiments were mainly carried out at 77°K. The observed resonance lines were identified as due to molybdenum in a +5 valence state. The values in the directions of the three orthorhombic crystal field axes are -1.7883, -1.8117, and -1.9125. The effective orbital factor, , was calculated to be 0.8784, indicating partial covalent bonding. Hyperfine lines from and were also observed, and their hyperfine interaction constants were calculated.
The resonance lines broadened at helium temperature due to saturation of the sample. The spin-lattice relaxation time is very long at this temperature. It increased from 10 to 600 sec as the temperature decreased from 4.2 to 1.3°K.
- Received 11 May 1962
DOI:https://doi.org/10.1103/PhysRev.128.151
©1962 American Physical Society