Ground-state energy eigenvalues and eigenfunctions are obtained by a variational method for an electron in the field of a finite, stationary, permanent electric dipole. The dipole moments studied cover the range from the minimum value required for binding ($D_{min}=0.6393\mathrm{} e{a}_0$) to $D=400\mathrm{} e{a}_0$, where the system is equivalent to the hydrogen atom perturbed slightly by a distant stationary negative charge. The eigenvalues obtained agree with those reported by Wallis, Herman, and Milnes, who determined them by another method in the range $D=0.84\mathrm{}e{a}_0 \mathrm{to} 30e{a}_0$. The normalized eigenfunctions display the manner in which the electronic charge density changes from that of the hydrogen atom at very large $D$ to a flat distribution approaching that which is characteristic of a zero-energy continuum state as the minimum moment is approached from above. Optimized variational wave functions for different values of $D$ are presented for use in other calculations. Contour maps and profiles of electronic charge density are shown for a number of values of $D$. Mean values of the powers -1, 1, and 2 of the distances of the electron from the dipole charges are also calculated.

• Received 12 April 1968

DOI:https://doi.org/10.1103/PhysRev.174.81