A Mathematical Treatment of the Electric Conductivity and Capacity of Disperse Systems I. The Electric Conductivity of a Suspension of Homogeneous Spheroids

Hugo Fricke
Phys. Rev. 24, 575 – Published 1 November 1924
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Abstract

Conductivity measurements may give values for (1) the specific conductivity, (2) the concentration or (3) eccentricity of form of the suspended particles of suspensions such as biological tissues, blood and cream. Mathematical theory. The following relation is derived: (kk11)(kk1+x)=ρ(k2k11)(k2k1+x), where k, k1 and k2 are the specific conductivities of the suspension, the suspending medium and the suspended spheroids, ρ is the volume concentration of the suspended spheroids, and x is a function of the ratio k2k1 and the ratio ab of the axis of symmetry of the spheroids to the other axis. For the case of spheres, x=2 and the formula reduces to that of Lorentz-Lorentz and Clausius-Mossotti. Curves are given showing the variation of x with k2k1 for various values of ab. Comparison with experimental data of Stewart for the conductivity of the blood of a dog (k2=0, ab=14.25, x=1.05) shows excellent agreement for concentration from 10 to 90 per cent. Also the observations of Oker-Blom for two suspensions of sand in salted gelatine, give in each case constant values of x for various concentrations.

  • Received 9 April 1924

DOI:https://doi.org/10.1103/PhysRev.24.575

©1924 American Physical Society

Authors & Affiliations

Hugo Fricke

  • Department of Bio-Physics, Cleveland Clinic Foundation, Cleveland, Ohio

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Issue

Vol. 24, Iss. 5 — November 1924

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