Continuum orbitals, complex scaling problem, and the extended virial theorem

Erkki Brändas and Piotr Froelich
Phys. Rev. A 16, 2207 – Published 1 December 1977
PDFExport Citation

Abstract

A complex scale transformation of the time-independent Schrödinger equation leads to a symmetric eigenvalue problem containing both bound states and resonance (complex) eigenvalues as solutions. An extended virial theorem is stated, and its necessary fulfillment is pointed out. The latter, in conjunction with a symmetric stationary principle, allows for determination of resonance (complex) eigenvalues by means of elementary matrix manipulations. Application to the Stark effect in the hydrogen atom shows agreement with previous calculations based on numerical integration.

  • Received 24 November 1976

DOI:https://doi.org/10.1103/PhysRevA.16.2207

©1977 American Physical Society

Authors & Affiliations

Erkki Brändas and Piotr Froelich

  • Quantum Chemistry Group, University of Uppsala, Box 518, S-751 20 Uppsala, Sweden

References (Subscription Required)

Click to Expand
Issue

Vol. 16, Iss. 6 — December 1977

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review A

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×