Dynamical fluctuations of droplet microemulsions and vesicles

Scott T. Milner and S. A. Safran
Phys. Rev. A 36, 4371 – Published 1 November 1987
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Abstract

The hydrodynamic fluctuations of nearly spherical vesicles and microemulsion droplets are considered. The incompressibility of the enclosed fluid and surfactant or lipid layer imposes a constraint of constant droplet volume and area on the fluctuations. These overdamped modes, driven by bending energy and damped by viscosity of the surrounding fluids, change the shape of the surface and may scatter neutrons or light. A dynamical structure factor S(q,t) is computed and a first frequency moment at fixed wave number ωchar(q) obtained. In the limit of a stiff droplet at fixed ‘‘excess area,’’ a new mode is obtained an overdamped oscillation among ellipsoidal shapes about the minimum-energy (usually prolate) shape. Prospects for observing this fluctuation are discussed.

  • Received 30 April 1987

DOI:https://doi.org/10.1103/PhysRevA.36.4371

©1987 American Physical Society

Authors & Affiliations

Scott T. Milner and S. A. Safran

  • Exxon Research and Engineering Company, Route 22 East, Annandale, New Jersey 08801

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Issue

Vol. 36, Iss. 9 — November 1987

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