Analytic form for the nonrelativistic Coulomb propagator

S. M. Blinder
Phys. Rev. A 43, 13 – Published 1 January 1991
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Abstract

An analytic form for the nonrelativistic Coulomb propagator is derived, thus resolving a long-standing problem in Feynman’s path-integral formulation of quantum mechanics. Hostler’s formula for the Coulomb Green’s function is expanded according to the theorem of Mittag-Leffler, then Fourier transformed term by term to give the Coulomb propagator. The result is a discrete summation over the principal quantum number n, involving Whittaker, Laguerre, Hermite, and error functions. As is the case for other nonquadratic potentials, the Coulomb propagator does not have the canonical structure K=F exp(iS/ħ). Part of the expansion resembles a form derived by Crandall [J. Phys. A 16, 3005 (1983)] for the case of reflectionless potentials.

  • Received 12 September 1990

DOI:https://doi.org/10.1103/PhysRevA.43.13

©1991 American Physical Society

Authors & Affiliations

S. M. Blinder

  • Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109

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Vol. 43, Iss. 1 — January 1991

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