Quantum discord, as introduced by Olliver and Zurek [Phys. Rev. Lett. 88, 017901 (2001)], is a measure of the discrepancy between two natural yet different quantum analogs of the classical mutual information. This notion characterizes and quantifies quantumness of correlations in bipartite states from a measurement perspective, and is fundamentally different from the various entanglement measures in the entanglement vs separability paradigm. The phenomenon of nonzero quantum discord is a manifestation of quantum correlations due to noncommutativity rather than due to entanglement, and has interesting and significant applications in revealing the advantage of certain quantum tasks. We will evaluate analytically the quantum discord for a large family of two-qubit states, and make a comparative study of the relationships between classical and quantum correlations in terms of the quantum discord. We furthermore compare the quantum discord with the entanglement of formation, and illustrate that the latter may be larger than the former, although for separable states, the entanglement of formation always vanishes and thus is less than the quantum discord.

• Received 28 October 2007

DOI:https://doi.org/10.1103/PhysRevA.77.042303