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Mg32 (Zn,Al)49-type icosahedral quasicrystals formed by solid-state reaction and rapid solidification

W. A. Cassada, Y. Shen, S. J. Poon, and G. J. Shiflet
Phys. Rev. B 34, 7413(R) – Published 15 November 1986
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Abstract

Icosahedral quasicrystals of Al-Mg-Zn, Al-Mg-Cu, Al-Li-Zn, and Al-Li-Cu are formed by low-temperature annealing of solid-solution alloys. Comparison is made with icosahedral Al-Mg-Cu, Al-Mg-Zn, and Al-Li-Cu prepared by rapid solidification. The compositions of the icosahedral compounds formed by solid-state reaction are similar to those observed in the rapidly solidified samples. The stability of these new phases is discussed. X-ray line intensities are found to agree well with the computed intensities for a quasicrystalline model based on the (Mg-Zn-Al)-type decoration of the three-dimensional Penrose tiles.

  • Received 30 July 1986

DOI:https://doi.org/10.1103/PhysRevB.34.7413

©1986 American Physical Society

Authors & Affiliations

W. A. Cassada

  • Department of Materials Science, University of Virginia, Charlottesville, Virginia 22901

Y. Shen and S. J. Poon

  • Department of Physics, University of Virginia, Charlottesville, Virginia 22901

G. J. Shiflet

  • Department of Materials Science, University of Virginia, Charlottesville, Virginia 22901

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Vol. 34, Iss. 10 — 15 November 1986

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