Abstract
The electronic structure of copper oxides has been investigated by photoelectron (x-ray photoemission, ultraviolet photoemission), Auger electron, and bremsstrahlung isochromat spectroscopies. The experimental results are compared with one-electron band-structure calculations as well as with a cluster configuration interaction model. It is demonstrated that the results for O agree well with band theory, whereas those for CuO clearly show strong deviations which we argue are due to electron-correlation effects in the open-shell bands. From the comparison to cluster calculations we extract values for the and Coulomb interactions, the O to Cu charge transfer energy, and the degree of hybridization. From this we demonstrate that CuO is a charge-transfer gap insulator.
- Received 25 July 1988
DOI:https://doi.org/10.1103/PhysRevB.38.11322
©1988 American Physical Society