Abstract
Raman scattering has been performed on pure polycrystalline powder over a frequency range of 20–2500 . The phonon Raman lines appearing only between 250 and 1600 can be assigned to all the Raman-active vibrational modes (2+8) predicted for the isolated molecules, which suggests only minor effects of intermolecular coupling on the properties of molecular vibrations. A comparison of the spectra taken at room temperature and low temperature (150 K) shows no significant change of the vibrational Raman modes after an orientational ordering transition.
- Received 6 December 1991
DOI:https://doi.org/10.1103/PhysRevB.45.11437
©1992 American Physical Society