Abstract
The concentration dependence of optical phonons in the - system whose phase diagram exhibits a miscibility gap, has been studied by Raman scattering and Fourier-transform infrared spectroscopy. X-ray diffraction confirmed that the mixed oxides with intervals x=0.1 are a single uniform phase (tetragonal) except some x’s; no phase separation by spinodal decomposition could be avoided for x=0.3, 0.4, 0.5, and 0.6, characterizing x-ray-diffraction profiles by sidebands. The 449 and 610 Raman modes for never changed linearly in frequency and linewidth with x. It is stressed that the x dependence of optical phonons is predominated by the octahedral distortion in , where different/anisotropic compressibilities and thermal expansivities of each end member play a crucial role. Infrared-reflectance spectra consisting of the infrared-active and modes between 50–900 , also changed systematically with x in . The concentration dependence of optical phonons in is discussed, from the viewpoint of the mode behavior of mixed crystals. © 1996 The American Physical Society.
- Received 17 August 1995
DOI:https://doi.org/10.1103/PhysRevB.53.8442
©1996 American Physical Society