Abstract
Optical absorption and electron paramagnetic resonance (EPR) have been applied in parallel to investigate :Cr[0.1%] and :Cr[0.1%], Mg[X%] crystals (X=2, 4, 5, 5.5, and 6). From the data obtained, it has been concluded that ions occupy both and sites. In Mg undoped crystals the optical absorption and EPR spectra are attributed to ions in site. In crystals with Mg doping levels greater than 4.6 mol % both and sites are occupied, their relative concentration being governed by the content. The double occupancy affects the overall absorption spectrum, giving rise to reproducible color changes in the crystal. Finally, the threshold found for the occupation of ions in sites is discussed considering the different models related to the nonstoichiometry of . © 1996 The American Physical Society.
- Received 9 February 1996
DOI:https://doi.org/10.1103/PhysRevB.54.13042
©1996 American Physical Society