Abstract
An EPR study of the Tl-doped PbCl crystals x-ray irradiated at low temperature reveals the presence, besides known spectra attributed to hole-trapped Tl centers and self-trapped-electron (STEL) centers, of an additional strongly anisotropic set of lines consisting of an intense doublet and several weaker satellite lines spread over a large magnetic-field range. The quantitative analysis of the EPR spectrum shows the corresponding paramagnetic center to be a bent molecular ion (PbTl) resulting from electron trapping at a pair of substitutional and Tl ions. Its formation suggests the electron trapping at pairs of neighboring cations is a more general characteristic of this material, with possible relevance in photolysis and exciton localization properties.
- Received 19 June 1997
DOI:https://doi.org/10.1103/PhysRevB.57.1
©1998 American Physical Society