Anharmonicity, vibrational instability, and the Boson peak in glasses

V. L. Gurevich, D. A. Parshin, and H. R. Schober
Phys. Rev. B 67, 094203 – Published 17 March 2003
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Abstract

We show that a vibrational instability of the spectrum of weakly interacting quasilocal harmonic modes creates the maximum in the inelastic scattering intensity in glasses, the Boson peak. The instability, limited by anharmonicity, causes a complete reconstruction of the vibrational density of states (DOS) below some frequency ωc, proportional to the strength of interaction. The DOS of the new harmonic modes is independent of the actual value of the anharmonicity. It is a universal function of frequency depending on a single parameter — the Boson peak frequency ωb which is a function of interaction strength. The excess of the DOS over the Debye value is ω4 at low frequencies and linear in ω in the interval ωbωωc. Our results are in an excellent agreement with recent experimental studies.

  • Received 30 July 2002

DOI:https://doi.org/10.1103/PhysRevB.67.094203

©2003 American Physical Society

Authors & Affiliations

V. L. Gurevich

  • Solid State Physics Division, A. F. Ioffe Institute, 194021, Saint Petersburg, Russia

D. A. Parshin

  • Saint Petersburg State Technical University, 195251, Saint Petersburg, Russia

H. R. Schober

  • Institut für Festkörperforschung, Forschungszentrum Jülich, D-52425, Jülich, Germany

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Vol. 67, Iss. 9 — 1 March 2003

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