Optically isotropic and monoclinic ferroelectric phases in $\text{Pb}({\text{Zr}}_{1\ensuremath{-}x}{\text{Ti}}_{x}){\text{O}}_{3}$ (PZT) single crystals near morphotropic phase boundary

Optically isotropic and monoclinic ferroelectric phases in $Pb ({Zr}_{1 - x} {Ti}_{x}) O_{3}$ (PZT) single crystals near morphotropic phase boundary

Alexei A. Bokov, Xifa Long, and Zuo-Guang Ye

Phys. Rev. B 81, 172103 – Published 24 May 2010

Abstract

We report the finding of unusual scale-dependent symmetry below the ferroelectric Curie temperature in the perovskite $Pb ({Zr}_{1 - x} {Ti}_{x}) O_{3}$ single crystals of morphotropic phase boundary compositions. The crystals of tetragonal symmetry on submicrometer scale exhibit a macroscopic (optically determined) cubic symmetry. This peculiar optical isotropy is explained by the anomalously small size of tetragonal ferroelectric domains. Upon further cooling the crystals transform to the phase consisting of micrometer-sized domains of monoclinic symmetry.