Atomic geometry and electron structure of the GaTe(102¯) surface

L. V. Yashina, R. Püttner, A. A. Volykhov, P. Stojanov, J. Riley, S. Yu. Vassiliev, A. N. Chaika, S. N. Dedyulin, M. E. Tamm, D. V. Vyalikh, and A. I. Belogorokhov
Phys. Rev. B 85, 075409 – Published 13 February 2012

Abstract

The natural cleavage plane (102¯) of a layered compound GaTe possesses unique properties due to high in-plain anisotropy with the corresponding lattice constant of 1.18 nm. The structure and electronic properties of the GaTe (102¯) clean surfaces have been studied both experimentally, using photoelectron spectroscopy, low-energy electron diffraction (LEED), and scanning tunneling microscopy, and theoretically, using density functional theory. The results clearly indicate a monoclinic structure of the surface layer, with no pronounced reconstruction or relaxation of the surface observed. This finding contradicts the previous LEED study, where a surface monoclinic-hexagonal phase transformation was reported. The GaTe (102¯) surface is found to be quite stable in time and resistant to oxidation. This makes gallium monotelluride an attractive substrate for growth of one-dimensional metal structures.

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  • Received 9 December 2010

DOI:https://doi.org/10.1103/PhysRevB.85.075409

©2012 American Physical Society

Authors & Affiliations

L. V. Yashina1, R. Püttner2, A. A. Volykhov1, P. Stojanov3, J. Riley3, S. Yu. Vassiliev1, A. N. Chaika4, S. N. Dedyulin1, M. E. Tamm1, D. V. Vyalikh5, and A. I. Belogorokhov6

  • 1Department of Chemistry, Moscow State University, Leninskie gory 1, 119991 Moscow, Russia
  • 2Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, D-14195 Berlin-Dahlem, Germany
  • 3Department of Physics, La Trobe University, Victoria 3086, Australia
  • 4Institute of Solid State Physics RAS, Academician Ossipyan str., 2, Chernogolovka, 142432 Moscow region, Russia
  • 5Institut für Festkörperphysik, Technische Universiät Dresden, Zellescher Weg 16, D-01062 Dresden, Germany
  • 6Federal State Research and Design Institute of Rare Metal Industry “GIREDMET,” B.Tolmachevsky lane 5-1, 119017 Moscow, Russia

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Issue

Vol. 85, Iss. 7 — 15 February 2012

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