Associating-polymer effects in a Hele-Shaw experiment

H. Zhao and J. V. Maher
Phys. Rev. E 47, 4278 – Published 1 June 1993
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Abstract

Pattern formation is studied by injecting water into a radial Hele-Shaw cell filled with an aqueous solution of hydrophobically terminated polyoxyethylene, which forms a reversible associating network in water. A crossover from fingering pattern to fracturing pattern is demonstrated as the injection rate exceeds a threshold value. The fingering-fracturing transition is sufficiently abrupt that no gradual crossover has been observed within our limits of experimental control, and it is found to be consistent with a Deborah-number scaling, except for homopolymers (where the hydrophobic end caps are replaced by hydroxyl groups) for which the fingering-fracturing transition was never observed.

  • Received 18 February 1993

DOI:https://doi.org/10.1103/PhysRevE.47.4278

©1993 American Physical Society

Authors & Affiliations

H. Zhao and J. V. Maher

  • Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, Pennsylvania 15260

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Vol. 47, Iss. 6 — June 1993

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