Static and dynamic collective correlations of polymer brushes

J. F. Marko and Amitabha Chakrabarti
Phys. Rev. E 48, 2739 – Published 1 October 1993
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Abstract

We report the results from a detailed Monte Carlo study of dynamic concentration fluctuations of a two-component grafted polymer ‘‘brush.’’ We compute the correlations at long length scales and their associated characteristic relaxation times, which could be measured in a dynamic scattering experiment. We find that the dynamic concentration fluctuations are dominated by in-plane contributions due to lateral chain fluctuations.

  • Received 1 February 1993

DOI:https://doi.org/10.1103/PhysRevE.48.2739

©1993 American Physical Society

Authors & Affiliations

J. F. Marko

  • Laboratory of Atomic and Solid State Physics, Clark Hall, Cornell University, Ithaca, New York 14853-2501

Amitabha Chakrabarti

  • Department of Physics, Kansas State University, Manhattan, Kansas 66506

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Vol. 48, Iss. 4 — October 1993

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