Weakly nonlinear morphological instability of a spherical crystal growing from a pure undercooled melt

Partha P. Debroy and Robert F. Sekerka
Phys. Rev. E 51, 4608 – Published 1 May 1995
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Abstract

We develop a weakly nonlinear morphological stability analysis for a sphere growing from its pure undercooled melt. For a sphere perturbed by a specific planform (a single spherical harmonic) we perform an expansion in the planform amplitude, A, to calculate the nonlinear critical radius (above which the chosen planform will be unstable for finite A), to lowest order in A, by setting the normal velocity corresponding to the fundamental perturbing mode to zero. We study the nonlinear critical radius as a function of the amplitude to identify the various bifurcations, which are transcritical (requiring an expansion to second order in A) for planforms generating physically distinct shapes for positive and negative amplitudes, and subcritical or supercritical (requiring an expansion to third order in A) for planforms for which the positive and negative amplitude shapes are related by rotation or translation. Bifurcations that are not transcritical are subcritical, except for a few harmonics of lower order or extreme ratios of the thermal conductivity in the solid to that in the liquid. We also treat the anomalous case of a perturbation by a first-order spherical harmonic (which is neutrally stable according to the linear theory, corresponding to a translation without any shape change) and observe that the second harmonic becomes unstable before the perturbing mode itself.

  • Received 31 May 1994

DOI:https://doi.org/10.1103/PhysRevE.51.4608

©1995 American Physical Society

Authors & Affiliations

Partha P. Debroy

  • Department of Physics, The Cooper Union, New York, New York 10003

Robert F. Sekerka

  • Departments of Physics and Mathematics, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213

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Vol. 51, Iss. 5 — May 1995

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