Shear-induced phase separation of complex fluids: The role of flow-concentration coupling

Véronique Schmitt, Carlos M. Marques, and François Lequeux
Phys. Rev. E 52, 4009 – Published 1 October 1995
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Abstract

We propose a classification scheme for the instabilities that might arise in sheared complex fluids. A central role is played by the coupling between the flow and the solute concentration, which is a combination of the parameters describing (a) the tendency of solute molecules to migrate to regions of small or high shear rates and (b) the variation of the viscosity with concentration. Using a mean field approach, we show that the nature and the geometry of the instability can be predicted from the knowledge of the coupling parameter, the diffuson coefficient, and the derivative of the stress with respect to the shear rate. We also successfully compare a description of the variation of the stress at and just beyond the instability threshold, with experimental results from a wormlike surfactant solution of CPClO3.

  • Received 1 February 1995

DOI:https://doi.org/10.1103/PhysRevE.52.4009

©1995 American Physical Society

Authors & Affiliations

Véronique Schmitt, Carlos M. Marques, and François Lequeux

  • Laboratoire Ultrasons et Dynamique des Fluides Complexes, URA 851 CNRS, Institut Le Bel, 4, Rue Blaise Pascal 67070 Strasbourg Cedex, France
  • Institut Charles Sadron, UPR 022 CNRS, 6, Rue Boussingault, 67000 Strasbourg Cedex, France

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Issue

Vol. 52, Iss. 4 — October 1995

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