Orientations of the lamellar phase of block copolymer melts under oscillatory shear flow

A. N. Morozov and J. G. E. M. Fraaije
Phys. Rev. E 65, 031803 – Published 21 February 2002
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Abstract

We develop a theory to describe the reorientation phenomena in the lamellar phase of block copolymer melts under reciprocating shear flow. We show that, similar to the steady shear, the oscillating flow anisotropically suppresses fluctuations and gives rise to the transition. The experimentally observed high-frequency reverse transition is explained in terms of interaction between the melt and the shear-cell walls.

  • Received 15 June 2001

DOI:https://doi.org/10.1103/PhysRevE.65.031803

©2002 American Physical Society

Authors & Affiliations

A. N. Morozov1,2,* and J. G. E. M. Fraaije2

  • 1Instituut-Lorentz for Theoretical Physics, Leiden University, P.O. Box 9506, 2300 RA Leiden, The Netherlands
  • 2Soft Condensed Matter Group, LIC, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands

  • *Email address: morozov@lorentz.leidenuniv.nl

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Vol. 65, Iss. 3 — March 2002

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