Aging and nonlinear rheology in suspensions of polyethylene oxide–protected silica particles

Caroline Derec, Guylaine Ducouret, Armand Ajdari, and François Lequeux
Phys. Rev. E 67, 061403 – Published 23 June 2003
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Abstract

In an attempt to establish connections between classical rheology and aging in paste colloidal suspensions, we report in this paper a large set of experimental results on a given system. We have studied suspensions of polyethylene oxide–protected silica particles and performed classical rheology experiments that exhibit a very nonlinear behavior. We have then evidenced aging through stress relaxation as observed in various glassy systems, and finally show other manifestations of aging through various rheological experiments. Qualitative agreement between these experimental results and the predictions of a simple model suggests that the behavior observed experimentally is governed by the competition between aging and mechanically induced rejuvenation.

  • Received 2 December 2002

DOI:https://doi.org/10.1103/PhysRevE.67.061403

©2003 American Physical Society

Authors & Affiliations

Caroline Derec1,*, Guylaine Ducouret2, Armand Ajdari1, and François Lequeux2

  • 1Physico-Chimie Théorique, UMR CNRS-ESPCI 7083, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 5, France
  • 2Physico-Chimie Macromoléculaire, UMR CNRS-ESPCI 7615, ESPCI, 10 rue Vauquelin, 75231 Paris Cedex 5, France

  • *Present address: PMMH, UMR CNRS-ESPCI 7636. Email address: derec@pmmh.espci.fr

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Vol. 67, Iss. 6 — June 2003

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