Random networks of cross-linked directed polymers

Stephan Ulrich, Annette Zippelius, and Panayotis Benetatos
Phys. Rev. E 81, 021802 – Published 19 February 2010

Abstract

We explore the effect of random permanent cross-links on a system of directed polymers confined between two planes with their end points free to slide on them. We treat the cross-links as quenched disorder and we use a semimicroscopic replica field theory to study the structure and elasticity of this system. Upon increasing the cross-link density, we get a continuous gelation transition signaled by the emergence of a finite in-plane localization length. The distribution of localization length turns out to depend on the height along the preferred direction of the directed polymers. The gelation transition also gives rise to a finite in-plane shear modulus which we calculate and turns out to be universal, i.e., independent of the energy and length scales of the polymers and the cross-links. Using a symmetry argument, we show that cross-links of negligible extent along the preferred axis of the directed polymers do not cause any renormalization to the tilt modulus of the uncross-linked system.

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  • Received 17 November 2009

DOI:https://doi.org/10.1103/PhysRevE.81.021802

©2010 American Physical Society

Authors & Affiliations

Stephan Ulrich1, Annette Zippelius1,2, and Panayotis Benetatos1,3

  • 1Institute for Theoretical Physics, Georg-August-Universität-Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany
  • 2Max Planck Institute for Dynamics & Self-Organization, Bunsenstraße 10, 37073 Göttingen, Germany
  • 3Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, 19 J. J. Thomson Avenue, Cambridge CB3 0HE, United Kingdom

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Vol. 81, Iss. 2 — February 2010

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