Abstract
A fluid confined between two parallel walls that exert different (competitive) surface fields may exhibit phase equilibria strikingly different from those found for equal fields. Macroscopic arguments and an explicit mean-field analysis predict that if the fields are such that the fluid wets one wall and dries the other (above a certain critical wetting transition temperature ) coexistence of two phases can only occur, for finite wall separation L, when T<,L, where the critical temperature ,L lies below . A scaling Ansatz suggests & where is the exponent that describes the growth of the wetting layer.
- Received 10 October 1989
DOI:https://doi.org/10.1103/PhysRevLett.64.439
©1990 American Physical Society