Scaling of the α relaxation in low-molecular-weight glass-forming liquids and polymers

Andreas Schönhals, Friedrich Kremer, and Eckhard Schlosser
Phys. Rev. Lett. 67, 999 – Published 19 August 1991
PDFExport Citation

Abstract

By measuring the complex dielectric susceptibility over 15 decades in frequency we compare the α relaxation in low-molecular-weight glass-forming liquids and polymers. To describe the scaling behavior of the α relaxation, a minimal set of four parameters is necessary, the mean relaxation time, the dielectric strength, and two shape parameters, describing the low- and high-frequency wings of the relaxation function, in pronounced contrast to a recently published scaling function.

  • Received 25 April 1991

DOI:https://doi.org/10.1103/PhysRevLett.67.999

©1991 American Physical Society

Authors & Affiliations

Andreas Schönhals, Friedrich Kremer, and Eckhard Schlosser

  • Zentralinstitut für Organische Chemie, Rudower Chaussee 5, O-1199 Berlin, Federal Republic of Germany
  • Max-Planck-Institut für Polymerforschung, Postfach 31 48, W-6500 Mainz, Federal Republic of Germany

Comments & Replies

Comment on ‘‘Scaling of the α relaxation in low-molecular-weight glass-forming liquids and polymers’’

Narayanan Menon and Sidney R. Nagel
Phys. Rev. Lett. 71, 4095 (1993)

Schönhals, Kremer, and Stickel reply

A. Schönhals, F. Kremer, and F. Stickel
Phys. Rev. Lett. 71, 4096 (1993)

References (Subscription Required)

Click to Expand
Issue

Vol. 67, Iss. 8 — 19 August 1991

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Letters

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×