Abstract
The observation of sequential attachment of two electrons to the molecule and the subsequent autodetachment of the dianion is reported. Remarkably, the cross section for attaching the second electron is estimated to be of the same order as that for adding the first electron. The measured lifetime for autodetachment of is in accord with calculations assuming “thermionic emission” from the vibrationally hot dianion. The first and second electron affinities of the two low-lying and isomers of are calculated using density functional theory to be and , respectively.
- Received 9 December 1996
DOI:https://doi.org/10.1103/PhysRevLett.78.4367
©1997 American Physical Society