An anomalous negative temperature dependence of electrical resistivity has been observed in $({\mathrm{Fe}}_{1-x}{\mathrm{V}}_x{)}_3\mathrm{Al}$ alloys with V compositions up to $x=0.35\mathrm{}$. In particular, the Heusler-type ${\mathrm{Fe}}_2\mathrm{VAl}$ compound is found to be on the verge of magnetic ordering and to exhibit a semiconductorlike behavior with the resistivity reaching $3000\mu \Omega \mathrm{cm}$ at 2 K, in spite of the possession of a clear Fermi cutoff as revealed in photoemission valence-band spectra. A substantial mass enhancement deduced from specific heat measurements suggests that ${\mathrm{Fe}}_2\mathrm{VAl}$ is a possible candidate for a $3d$ heavy-fermion system.

• Received 7 March 1997

DOI:https://doi.org/10.1103/PhysRevLett.79.1909